A Novel Zeolite-Induced Population of a Planar Viologen Conformation. New Viologen Charge Transfer Complexes and Alkene/Viologen/Zeolite Arrays
Identifieur interne : 001105 ( Main/Exploration ); précédent : 001104; suivant : 001106A Novel Zeolite-Induced Population of a Planar Viologen Conformation. New Viologen Charge Transfer Complexes and Alkene/Viologen/Zeolite Arrays
Auteurs : Andrea Pace [Danemark] ; Edward L. Clennan [Danemark, États-Unis] ; Frank Jensen [Danemark] ; Jamie Singleton [Danemark]Source :
- The Journal of Physical Chemistry B [ 1520-6106 ] ; 2004.
English descriptors
- Teeft :
- Absorbance value, Acetonitrile, Acetonitrile solution, Aqueous solution, Binding constant, Blue color, Broad band, Brown solid, Cation, Chem, Colorimetric test, Datum, Degli studi, Diffuse reflectance spectroscopy, Diffuse reflectance spectrum, Doped zeolite, Equilibrium constant, Excitation energy, Force field, Hypsochromic shift, Influence product distribution, Intrazeolite, Ionization potential, John wiley son, Loading level, Methyl viologen, Namqy, Namvy, Odense university, Phys, Planar, Planar conformation, Planar geometry, Planar radical cation, Radical cation, Raman spectroscopy, Raman spectrum, Reflectance, Rotational energy profile, Several time, Small amount, Solid state, Solvated electron, Straight line, Suspension overnight, Unit cell, Viologen, Wash solution, Zeolite, Zeolite array, Zeolite framework.
Abstract
A rare example of a novel zeolite-induced conformational change and a mechanism for this process are suggested in order to rationalize an unexpected spontaneous intrazeolite reduction observed during preparation of a new viologen (MQ2+)-doped zeolite (NaY). In addition, the formations of six new alkene/viologen/zeolite charge transfer (CT) arrays using NaMQY and the previously reported NaMVY are also reported. The binding constants between MQ2+ and MV2+ and 2,3-dimethyl-2-butene (TME) were determined using the Benesi−Hildebrand approach, and the stabilities of these CT complexes are compared to their intrazeolite analogue.
Url:
DOI: 10.1021/jp036200p
Affiliations:
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Clennan</name><affiliation wicri:level="1"><country xml:lang="fr">Danemark</country><wicri:regionArea>Department of Chemistry, University of Wyoming, Laramie, Wyoming 82071, Dipartimento di ChimicaOrganica “E. Paternò”, Università degli Studi di Palermo, Viale delle Scienze, Parco d'Orleans II,90128, Palermo, Italy, and Department of Chemistry, Odense University, DK-5230 Odense M.</wicri:regionArea><wicri:noRegion>DK-5230 Odense M.</wicri:noRegion></affiliation><affiliation></affiliation><affiliation wicri:level="1"><country wicri:rule="url">États-Unis</country></affiliation></author><author><name sortKey="Jensen, Frank" sort="Jensen, Frank" uniqKey="Jensen F" first="Frank" last="Jensen">Frank Jensen</name><affiliation wicri:level="1"><country xml:lang="fr">Danemark</country><wicri:regionArea>Department of Chemistry, University of Wyoming, Laramie, Wyoming 82071, Dipartimento di ChimicaOrganica “E. 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In addition, the formations of six new alkene/viologen/zeolite charge transfer (CT) arrays using NaMQY and the previously reported NaMVY are also reported. The binding constants between MQ2+ and MV2+ and 2,3-dimethyl-2-butene (TME) were determined using the Benesi−Hildebrand approach, and the stabilities of these CT complexes are compared to their intrazeolite analogue.</div></front></TEI><affiliations><list><country><li>Danemark</li><li>États-Unis</li></country></list><tree><country name="Danemark"><noRegion><name sortKey="Pace, Andrea" sort="Pace, Andrea" uniqKey="Pace A" first="Andrea" last="Pace">Andrea Pace</name></noRegion><name sortKey="Clennan, Edward L" sort="Clennan, Edward L" uniqKey="Clennan E" first="Edward L." last="Clennan">Edward L. Clennan</name><name sortKey="Jensen, Frank" sort="Jensen, Frank" uniqKey="Jensen F" first="Frank" last="Jensen">Frank Jensen</name><name sortKey="Singleton, Jamie" sort="Singleton, Jamie" uniqKey="Singleton J" first="Jamie" last="Singleton">Jamie Singleton</name></country><country name="États-Unis"><noRegion><name sortKey="Clennan, Edward L" sort="Clennan, Edward L" uniqKey="Clennan E" first="Edward L." last="Clennan">Edward L. Clennan</name></noRegion></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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